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hydrogen rich environment and oscillators

PK
Poul-Henning Kamp
Tue, Dec 13, 2022 9:24 PM

Lux, Jim via time-nuts writes:

Is there a cheap connector/feedthrough that can take 100 psi or so to be
able to make measurements "in-situ"?

Use a window and optical transmission ?

--
Poul-Henning Kamp      | UNIX since Zilog Zeus 3.20
phk@FreeBSD.ORG        | TCP/IP since RFC 956
FreeBSD committer      | BSD since 4.3-tahoe
Never attribute to malice what can adequately be explained by incompetence.

-------- Lux, Jim via time-nuts writes: > Is there a cheap connector/feedthrough that can take 100 psi or so to be > able to make measurements "in-situ"? Use a window and optical transmission ? -- Poul-Henning Kamp | UNIX since Zilog Zeus 3.20 phk@FreeBSD.ORG | TCP/IP since RFC 956 FreeBSD committer | BSD since 4.3-tahoe Never attribute to malice what can adequately be explained by incompetence.
LJ
Lux, Jim
Tue, Dec 13, 2022 9:35 PM

On 12/13/22 1:24 PM, Poul-Henning Kamp wrote:


Lux, Jim via time-nuts writes:

Is there a cheap connector/feedthrough that can take 100 psi or so to be
able to make measurements "in-situ"?

Use a window and optical transmission ?

It's hard to get power in with optical transmission.

Say you have your favorite 10811 based GPSDO and you want to see how
it's going to work in your diving bell loaded with heliox (with a coax
cable to a floating buoy with the GNSS choke ring antenna) - but not
really...

This is sort of different from the whole He, H2 question - but it raised
the interesting question of operating devices at pressures other than
room temp.  We've talked a lot on the list about schemes of varying
complexity to thermally isolate an oscillator - well, putting it in even
a partial vacuum might  be effective, one really wants to get the MFP to
"bigger" than the gap between device and wall, so convection stops being
an issue: then it's just radiation, but even if you pump down to, say,
1/100th bar, the bulk thermal conductivity will be (I think) 1/100th of
what it is in "room air".

On 12/13/22 1:24 PM, Poul-Henning Kamp wrote: > -------- > Lux, Jim via time-nuts writes: > >> Is there a cheap connector/feedthrough that can take 100 psi or so to be >> able to make measurements "in-situ"? > Use a window and optical transmission ? > It's hard to get power in with optical transmission. Say you have your favorite 10811 based GPSDO and you want to see how it's going to work in your diving bell loaded with heliox (with a coax cable to a floating buoy with the GNSS choke ring antenna) - but not really... This is sort of different from the whole He, H2 question - but it raised the interesting question of operating devices at pressures other than room temp.  We've talked a lot on the list about schemes of varying complexity to thermally isolate an oscillator - well, putting it in even a partial vacuum might  be effective, one really wants to get the MFP to "bigger" than the gap between device and wall, so convection stops being an issue: then it's just radiation, but even if you pump down to, say, 1/100th bar, the bulk thermal conductivity will be (I think) 1/100th of what it is in "room air".
SH
Steve Hendrix, P.E.
Tue, Dec 13, 2022 9:36 PM

On 2022-12-13 04:10 PM, Lux, Jim via time-nuts wrote:

yeah, since the flammable range for H2 is pretty wide.

I recall from a number of decades ago when I worked on aerospace systems
that used large amounts of H2, that the lower explosive limit for
hydrogen in air was 4%, so we had all our sensors set to alarm at 2%.
Keep in mind, though, that if hydrogen gets loose it can burn, but if
pure oxygen gets loose, EVERYTHING will burn. And as others said, a tiny
quantity only has so much energy available.

Steve Hendrix

On 2022-12-13 04:10 PM, Lux, Jim via time-nuts wrote: > yeah, since the flammable range for H2 is pretty wide. I recall from a number of decades ago when I worked on aerospace systems that used large amounts of H2, that the lower explosive limit for hydrogen in air was 4%, so we had all our sensors set to alarm at 2%. Keep in mind, though, that if hydrogen gets loose it can burn, but if pure oxygen gets loose, EVERYTHING will burn. And as others said, a tiny quantity only has so much energy available. Steve Hendrix
BC
Bob Camp
Tue, Dec 13, 2022 9:37 PM

Hi

Given that you can keep feeding gas to the pot ( = minor leaks in the back yard
aren’t that big a deal …), grab a tube of epoxy and attack the pressurized side of
whatever connector happens to be handy. Probably do several layers. Run
carefully spaced bare wires through the epoxy.

My choice for a connector would be something circular. I’d go that way  just to
make the mounting hole easy to drill and later maybe plug with a bolt. A 4 pin “mic
connector” comes to mind ( and there’s one sitting loose right over there ….).
Power, ground, signal out, signal in maybe.

Epoxy may be overkill in this case. RTV might do the trick. It certainly would be
easier to strip off afterwords. A lot depends on just how “valuable” the pressure
pot happens to be …...

Bob

On Dec 13, 2022, at 4:10 PM, Lux, Jim jim@luxfamily.com wrote:

On 12/13/22 11:48 AM, Bob Camp wrote:

Hi

The MIL-STD 202 folks seemed to be quite happy with a 10% mix of He and whatever. My guess is
that you could fill the pressure chamber with your water sourced H2 and then blow it up to 50 PSI
with the shop compressor.

The obvious disadvantage of any process using H2 is fire / explosion. I’m not 100% sure this is the
approach I’d want to take …..

yeah, since the flammable range for H2 is pretty wide.

So do it in the back yard, not the garage or living room.

And if it's just a few cc of H2, I'd think the pressure pot would contain any "momentary overpressure"

This does bring up an interesting idea for time-nut-ty experimentation.  Is there a cheap connector/feedthrough that can take 100 psi or so to be able to make measurements "in-situ"? Hermetic RF connectors are available (not cheap new, but perhaps surplus), but I've only used them for 15 psi differential (e.g. atmosphere outside to vacuum inside). I've also used non-resistor spark plugs as HV hermetic feed throughs (there's some specific Champion number that has a particularly long reach).  Something like a D-sub with a dozen or so pins might be convenient, especially if it's round (since round holes are easier to drill)

Hi Given that you can keep feeding gas to the pot ( = minor leaks in the back yard aren’t that big a deal …), grab a tube of epoxy and attack the pressurized side of whatever connector happens to be handy. Probably do several layers. Run carefully spaced bare wires through the epoxy. My choice for a connector would be something circular. I’d go that way just to make the mounting hole easy to drill and later maybe plug with a bolt. A 4 pin “mic connector” comes to mind ( and there’s one sitting loose right over there ….). Power, ground, signal out, signal in maybe. Epoxy may be overkill in this case. RTV might do the trick. It certainly would be easier to strip off afterwords. A lot depends on just how “valuable” the pressure pot happens to be …... Bob > On Dec 13, 2022, at 4:10 PM, Lux, Jim <jim@luxfamily.com> wrote: > > On 12/13/22 11:48 AM, Bob Camp wrote: >> Hi >> >> The MIL-STD 202 folks seemed to be quite happy with a 10% mix of He and whatever. My guess is >> that you could fill the pressure chamber with your water sourced H2 and then blow it up to 50 PSI >> with the shop compressor. >> >> The obvious disadvantage of any process using H2 is fire / explosion. I’m not 100% sure this is the >> approach I’d want to take ….. > > > yeah, since the flammable range for H2 is pretty wide. > > So do it in the back yard, not the garage or living room. > > And if it's just a few cc of H2, I'd think the pressure pot would contain any "momentary overpressure" > > > This does bring up an interesting idea for time-nut-ty experimentation. Is there a cheap connector/feedthrough that can take 100 psi or so to be able to make measurements "in-situ"? Hermetic RF connectors are available (not cheap new, but perhaps surplus), but I've only used them for 15 psi differential (e.g. atmosphere outside to vacuum inside). I've also used non-resistor spark plugs as HV hermetic feed throughs (there's some specific Champion number that has a particularly long reach). Something like a D-sub with a dozen or so pins might be convenient, especially if it's round (since round holes are easier to drill) >
PK
Poul-Henning Kamp
Tue, Dec 13, 2022 9:47 PM

Lux, Jim writes:

We've talked a lot on the list about schemes of varying
complexity to thermally isolate an oscillator - well, putting it in even
a partial vacuum might  be effective, [...]

The thing about vacuum is that you have to make sure you still get
rid of enough heat to not cook your devices.

I know of at least one early cube-sat which did not deploy it's
antenna, because somebody didnt heat-sink the FET which should have
delivered power to melt the launch-restraints.

--
Poul-Henning Kamp      | UNIX since Zilog Zeus 3.20
phk@FreeBSD.ORG        | TCP/IP since RFC 956
FreeBSD committer      | BSD since 4.3-tahoe
Never attribute to malice what can adequately be explained by incompetence.

-------- Lux, Jim writes: > We've talked a lot on the list about schemes of varying > complexity to thermally isolate an oscillator - well, putting it in even > a partial vacuum might  be effective, [...] The thing about vacuum is that you have to make sure you still get rid of enough heat to not cook your devices. I know of at least one early cube-sat which did not deploy it's antenna, because somebody didnt heat-sink the FET which should have delivered power to melt the launch-restraints. -- Poul-Henning Kamp | UNIX since Zilog Zeus 3.20 phk@FreeBSD.ORG | TCP/IP since RFC 956 FreeBSD committer | BSD since 4.3-tahoe Never attribute to malice what can adequately be explained by incompetence.
BC
Bob Camp
Tue, Dec 13, 2022 10:15 PM

Hi

If we are off to a stabilized / vacuum environment, it’s a pretty good bet that there
will be multiple sources of leaks / outgassing / whatever to mess things up. You
will have a pump of some sort to deal with what’s going on. The better you can make
things, the smaller a pump you would need. It’s still a pump and under some sort
of servo control ….. loop back to “pressure sensor is out of whack” a week or two
ago :)

Bob

On Dec 13, 2022, at 4:35 PM, Lux, Jim jim@luxfamily.com wrote:

On 12/13/22 1:24 PM, Poul-Henning Kamp wrote:


Lux, Jim via time-nuts writes:

Is there a cheap connector/feedthrough that can take 100 psi or so to be
able to make measurements "in-situ"?

Use a window and optical transmission ?

It's hard to get power in with optical transmission.

Say you have your favorite 10811 based GPSDO and you want to see how it's going to work in your diving bell loaded with heliox (with a coax cable to a floating buoy with the GNSS choke ring antenna) - but not really...

This is sort of different from the whole He, H2 question - but it raised the interesting question of operating devices at pressures other than room temp.  We've talked a lot on the list about schemes of varying complexity to thermally isolate an oscillator - well, putting it in even a partial vacuum might  be effective, one really wants to get the MFP to "bigger" than the gap between device and wall, so convection stops being an issue: then it's just radiation, but even if you pump down to, say, 1/100th bar, the bulk thermal conductivity will be (I think) 1/100th of what it is in "room air".

Hi If we are off to a stabilized / vacuum environment, it’s a pretty good bet that there will be multiple sources of leaks / outgassing / whatever to mess things up. You will have a pump of some sort to deal with what’s going on. The better you can make things, the smaller a pump you would need. It’s still a pump and under some sort of servo control ….. loop back to “pressure sensor is out of whack” a week or two ago :) Bob > On Dec 13, 2022, at 4:35 PM, Lux, Jim <jim@luxfamily.com> wrote: > > On 12/13/22 1:24 PM, Poul-Henning Kamp wrote: >> -------- >> Lux, Jim via time-nuts writes: >> >>> Is there a cheap connector/feedthrough that can take 100 psi or so to be >>> able to make measurements "in-situ"? >> Use a window and optical transmission ? >> > It's hard to get power in with optical transmission. > > Say you have your favorite 10811 based GPSDO and you want to see how it's going to work in your diving bell loaded with heliox (with a coax cable to a floating buoy with the GNSS choke ring antenna) - but not really... > > This is sort of different from the whole He, H2 question - but it raised the interesting question of operating devices at pressures other than room temp. We've talked a lot on the list about schemes of varying complexity to thermally isolate an oscillator - well, putting it in even a partial vacuum might be effective, one really wants to get the MFP to "bigger" than the gap between device and wall, so convection stops being an issue: then it's just radiation, but even if you pump down to, say, 1/100th bar, the bulk thermal conductivity will be (I think) 1/100th of what it is in "room air". > > >
PK
Poul-Henning Kamp
Wed, Dec 14, 2022 10:47 AM

Steve Hendrix, P.E. via time-nuts writes:

Keep in mind, though, that if hydrogen gets loose it can burn, but if
pure oxygen gets loose, EVERYTHING will burn. And as others said, a tiny
quantity only has so much energy available.

There is a very informative monograph from NASA (sorry, dont have a link
at hand) about their early experiences with cryogenic rocket fuel.

A particular interesting episode is where they have a leak in a LOX tank,
and then the firetruck of the emergency response catches fire because
they are downwind.

--
Poul-Henning Kamp      | UNIX since Zilog Zeus 3.20
phk@FreeBSD.ORG        | TCP/IP since RFC 956
FreeBSD committer      | BSD since 4.3-tahoe
Never attribute to malice what can adequately be explained by incompetence.

-------- Steve Hendrix, P.E. via time-nuts writes: > Keep in mind, though, that if hydrogen gets loose it can burn, but if > pure oxygen gets loose, EVERYTHING will burn. And as others said, a tiny > quantity only has so much energy available. There is a very informative monograph from NASA (sorry, dont have a link at hand) about their early experiences with cryogenic rocket fuel. A particular interesting episode is where they have a leak in a LOX tank, and then the firetruck of the emergency response catches fire because they are downwind. -- Poul-Henning Kamp | UNIX since Zilog Zeus 3.20 phk@FreeBSD.ORG | TCP/IP since RFC 956 FreeBSD committer | BSD since 4.3-tahoe Never attribute to malice what can adequately be explained by incompetence.
GE
glen english LIST
Mon, Jan 16, 2023 10:26 PM

Hi

I am embarking on building up a block - a common collector Butler
oscillator with an overtone  crystal at 98.304 MHz

on on FR4 , I've used the Philips NPN type  BFS17.

The results <=10 Hz phase noise were quite disappointing. (-69 @ 98 MHz)

Does anyone have any good suggestions. Maybe something slower (larger)
like a 2N5179 (or its SMT counterpart MMBT5179) will be better.

regards

glen

On 13/12/2022 11:14 am, Lux, Jim via time-nuts wrote:

On 12/12/22 2:43 PM, Alex Pumm

Hi I am embarking on building up a block - a common collector Butler oscillator with an overtone  crystal at 98.304 MHz on on FR4 , I've used the Philips NPN type  BFS17. The results <=10 Hz phase noise were quite disappointing. (-69 @ 98 MHz) Does anyone have any good suggestions. Maybe something slower (larger) like a 2N5179 (or its SMT counterpart MMBT5179) will be better. regards glen On 13/12/2022 11:14 am, Lux, Jim via time-nuts wrote: > On 12/12/22 2:43 PM, Alex Pumm
BC
Bob Camp
Tue, Jan 17, 2023 12:31 AM

Hi

If you are inside 10 ppm, it’s a good bet that you are in a region that is still influenced by the
resonator / oscillator Q. At 98 MHz this is an offset of about 1 KHz. First thing to worry about
is the Q of your resonator.

Past that, transistors vary a lot. This brand vs that brand matters. VHF transistors are rarely
well characterized for audio noise. Their performance vs spec is not a great thing to use as a
selection parameter.

Simple answer is always going to be: try it and see.

Probably better to look at 100Hz noise. At least there, you have pretty well defined limits as
to what’s ok, good, great, and impossible. As you go from -120 to -140 dbc/Hz, you pretty much
cover that entire range.

Bob

On Jan 16, 2023, at 5:26 PM, glen english LIST via time-nuts time-nuts@lists.febo.com wrote:

Hi

I am embarking on building up a block - a common collector Butler oscillator with an overtone  crystal at 98.304 MHz

on on FR4 , I've used the Philips NPN type  BFS17.

The results <=10 Hz phase noise were quite disappointing. (-69 @ 98 MHz)

Does anyone have any good suggestions. Maybe something slower (larger) like a 2N5179 (or its SMT counterpart MMBT5179) will be better.

regards

glen

On 13/12/2022 11:14 am, Lux, Jim via time-nuts wrote:

On 12/12/22 2:43 PM, Alex Pumm


time-nuts mailing list -- time-nuts@lists.febo.com
To unsubscribe send an email to time-nuts-leave@lists.febo.com

Hi If you are inside 10 ppm, it’s a good bet that you are in a region that is still influenced by the resonator / oscillator Q. At 98 MHz this is an offset of about 1 KHz. First thing to worry about is the Q of your resonator. Past that, transistors vary a lot. This brand vs that brand matters. VHF transistors are rarely well characterized for audio noise. Their performance vs spec is not a great thing to use as a selection parameter. Simple answer is always going to be: try it and see. Probably better to look at 100Hz noise. At least there, you have pretty well defined limits as to what’s ok, good, great, and impossible. As you go from -120 to -140 dbc/Hz, you pretty much cover that entire range. Bob > On Jan 16, 2023, at 5:26 PM, glen english LIST via time-nuts <time-nuts@lists.febo.com> wrote: > > Hi > > I am embarking on building up a block - a common collector Butler oscillator with an overtone crystal at 98.304 MHz > > on on FR4 , I've used the Philips NPN type BFS17. > > The results <=10 Hz phase noise were quite disappointing. (-69 @ 98 MHz) > > Does anyone have any good suggestions. Maybe something slower (larger) like a 2N5179 (or its SMT counterpart MMBT5179) will be better. > > regards > > glen > > On 13/12/2022 11:14 am, Lux, Jim via time-nuts wrote: >> On 12/12/22 2:43 PM, Alex Pumm > _______________________________________________ > time-nuts mailing list -- time-nuts@lists.febo.com > To unsubscribe send an email to time-nuts-leave@lists.febo.com
RK
Richard Karlquist
Tue, Jan 17, 2023 1:12 AM

Generally speaking, the 1/f noise at, say 10 Hz, for a crystal
oscillator is determined

entirely by the intrinsic noise of the crystal.  It's really hard to
screw up an oscillator

circuit so badly that it actually contributes anything to the oscillator
1/f noise.

For instance, I'm sure we will all agree that the HP 10811 is a pretty
decent oscillator.

FYI, essentially the same crystal is used in the E1938A that I designed.
Those two

oscillators have ENTIRELY different circuits.  Yet both achieve the same
close in

phase noise as what I measured for the intrinsic noise of the crystal.
By the way,

the HP 10811 uses a selected 2N5179 transistor.  But is NOT SELECTED FOR

1/f NOISE.  Instead it is selected for good gain at high DC collector
current, because

the HP engineer who designed it had trouble with the oscillator starting
up correctly,

in conjunction with the ALC circuit.

If you use the same output circuit for your oscillator as the 10811, you
will also

have no oscillator transistor contribution to far out phase noise.
This is all

very well documented if you want to read the details.

In a previous life, I designed many many 5th overtone oscillators.  Your
crystal

like the Croven ones I used in those days is not of the same caliber as
the

10811 crystal, so therefore it is even more unlikely that the transistor

you choose is going to make any difference.  I always locked my 5th OT

crystals to something like a 10544 oscillator to clean them up close in

using PLL synthesizers.  The 10811 hadn't been invented yet.

I hope this gets you back on the right track.


Rick Karlquist
N6RK

On 2023-01-16 14:26, glen english LIST via time-nuts wrote:

Hi

I am embarking on building up a block - a common collector Butler oscillator with an overtone  crystal at 98.304 MHz

on on FR4 , I've used the Philips NPN type  BFS17.

The results <=10 Hz phase noise were quite disappointing. (-69 @ 98 MHz)

Does anyone have any good suggestions. Maybe something slower (larger) like a 2N5179 (or its SMT counterpart MMBT5179) will be better.

regards

glen

On 13/12/2022 11:14 am, Lux, Jim via time-nuts wrote:

On 12/12/22 2:43 PM, Alex Pumm


time-nuts mailing list -- time-nuts@lists.febo.com
To unsubscribe send an email to time-nuts-leave@lists.febo.com

Generally speaking, the 1/f noise at, say 10 Hz, for a crystal oscillator is determined entirely by the intrinsic noise of the crystal. It's really hard to screw up an oscillator circuit so badly that it actually contributes anything to the oscillator 1/f noise. For instance, I'm sure we will all agree that the HP 10811 is a pretty decent oscillator. FYI, essentially the same crystal is used in the E1938A that I designed. Those two oscillators have ENTIRELY different circuits. Yet both achieve the same close in phase noise as what I measured for the intrinsic noise of the crystal. By the way, the HP 10811 uses a selected 2N5179 transistor. But is NOT SELECTED FOR 1/f NOISE. Instead it is selected for good gain at high DC collector current, because the HP engineer who designed it had trouble with the oscillator starting up correctly, in conjunction with the ALC circuit. If you use the same output circuit for your oscillator as the 10811, you will also have no oscillator transistor contribution to far out phase noise. This is all very well documented if you want to read the details. In a previous life, I designed many many 5th overtone oscillators. Your crystal like the Croven ones I used in those days is not of the same caliber as the 10811 crystal, so therefore it is even more unlikely that the transistor you choose is going to make any difference. I always locked my 5th OT crystals to something like a 10544 oscillator to clean them up close in using PLL synthesizers. The 10811 hadn't been invented yet. I hope this gets you back on the right track. --- Rick Karlquist N6RK On 2023-01-16 14:26, glen english LIST via time-nuts wrote: > Hi > > I am embarking on building up a block - a common collector Butler oscillator with an overtone crystal at 98.304 MHz > > on on FR4 , I've used the Philips NPN type BFS17. > > The results <=10 Hz phase noise were quite disappointing. (-69 @ 98 MHz) > > Does anyone have any good suggestions. Maybe something slower (larger) like a 2N5179 (or its SMT counterpart MMBT5179) will be better. > > regards > > glen > > On 13/12/2022 11:14 am, Lux, Jim via time-nuts wrote: > >> On 12/12/22 2:43 PM, Alex Pumm > _______________________________________________ > time-nuts mailing list -- time-nuts@lists.febo.com > To unsubscribe send an email to time-nuts-leave@lists.febo.com